Production of Nanostructured metal catalysts Nanostructured Metal

Supported Catalysts

Rh/g-Al₂O₃

Rhodium: metal particles ranging 1-2 nm in diameter

Rh/C

Excellent catalysts for hydrogenation, hydrosilylation, silylformilation reactions; they are largely more active than analogous commercial


Particles size distribution of a commercial Rh/g-Al₂O₃ sample		Particles size distribution of a MVS Rh/g-Al₂O₃ sample

Advanced nanostructured metal powders Catalysts by Small Metal Clusters, Production of Hetero Nanostructured metals catalysts, Homogeneous Heterogeneous Oxidation Polymerization catalysts,Hydrogenation catalysis, Metal vapors technology technique,Very active and selective New generation catalysts,Bimetallic catalytic systems

(PDMP = polydimethylphosphazene)

Applicative Aspects Polyorganophosphazenes, M. Gleria, R. De Jaeger, Eds. Nova Science Publ., New York (2004) pp.255-265

Gold: particle size distribution raging 4 nm in diameter

Au/g-Al₂O₃

Au/C

Valuable catalysts for hydrosilylation reactions

Particles size distribution of Au/C 1 % w/w sample

J. Organomet.Chem., 690 (2005) 1063

Particles size distribution of a Pd/C sample

Pd/PDMP

Excellent catalysts for Heck reactions, without valuable leaching of Pd

Particles size distribution of a Pd/PDMP sample

J. Oganomet. Chem., 681 (2003) 37

Palladium: metal particles ranging 1-2 nm in Pd/g-Al₂O₃ and Pd/C samples and 3-4 nm in Pd/PDMP catalysts

Pd/g-Al₂O₃

Pd/C

Very active hydrogenation catalysts

Ruthenium: metal particles ranging 2.4 nm in diameter

Ru/g-Al₂O₃

Ru/C

Very active arene hydrogenation catalysts

J. Organomet.Chem., 289 (2004) 639

Alkynes Silylformylation

Silylformylation reaction of 1-hexine with a commercial Rh/g-Al₂O₃ 5 w/w % and with an analogous system prepared via M V S technique

Synthesis and Methodologies in Inorganic Chemistry, L. Armalao, D. Barreca, S. Daolio, E. Tondello, P. A. Vigato, Eds. 2001, vol. 9, pp. 43-51

Cobalt: metal particles ranging 2.5 nm in diameter

Co/g-Al₂O₃

Co/C

Very active in Fischer-Tropsch reaction

Examples of the activity of supported catalysts prepared via MVS technique

Arene Hydrogenation


Hydrogenation reaction of aromatic compounds with a commercial Rh/g-Al₂O₃ 5 w/w % and with an analogous system prepared via M V S technique

Metal vapors technology

Production of Nanostructured metal catalysts Bimetallic catalytic systems, Metal vapors technology technique,Advanced nanostructured metal powders Catalysts by Small Metal Clusters, Homogeneous Heterogeneous Oxidation Polymerization catalysts, Production of Hetero Nanostructured metals catalysts,Very active and selective New generation catalysts,Hydrogenation catalysis

Homogeneous catalysis,Very active and selective catalysts,Metal vapors technique,Metal vapors technology,Hetero Nanostructured metal,Polymerization catalysts,Analyzing of Materials,New generation catalysts,Bimetallic catalytic systems,Nanostructured metal catalysts,Hydrogenation catalysts,Oxidation catalysts,Advanced nanostructured metal,Heterogeneous catalysis,Catalysis by Small Metal Clusters,Production of Nanostructured metal catalysts,Nanostructured metal powders,Advanced Catalysts,Carbon-Carbon coupling reactions catalysts, Nanostructured metals,Nanostructured Metal